Potentiometric Titration Principle Pdf
Redox titrations as for example the determination of vitamin C in orange juice normally require a platinum electrode. Sedimented dust and soil are tedious to prepare. Platinum or Au are used as metal indicator electrodes. Surface, Sea, ground, potable, and waste water.
It is thus impossible to cover all possible applications with one size of burette. Show related SlideShares at end. Molecular Compound Electrodes These contain a conventional electrode surrounded by a membrane that isolates or generates the analyte to which the electrode responds.
In special cases, the endpoint of the titration is detected by measuring the electric conductivity with a conductivity cell. When using a conductivity cell as sensor V-shaded curve the endpoint is calculated based on the crossing point of two tangents see picture in the center.
It gives the standard or known potential. The shape of the titration curve volume of titrant vs. The amount of titrant used depends on the type of analysis. The titrant is added by means of a burette.
What is a Titrator
These electrodes respond to the ionic activity of the electrode. Mainly two electrodes are used in the potentiometry.
The information is divided in several chapters. The presentation is successfully added In Your Favorites. To do this, two electrodes are used, an indicator electrode the glass electrode and metal ion indicator electrode and a reference electrode. Titration is a quantitative chemical analysis. Reference electrode is used as one half of the electrochemical cell for determining the potential of the given sample.
According to the type of sample analyzed and the indicator used, either the point below or the point above can be taken as endpoint. They are composed of the metal rod immersed in its metal solution. Carry out a blank titration. Switch the meter to standby and turn off the stirrer.
In such cases, the endpoint is calculated with tangents see picture on the right. The evaluation of endpoint must be done according to shape of the titration curve. Acid base titrations like for example the determination of acidity in fruit juice require a pH electrode as sensor. He found the greatest potential difference is achieved once all of the mercurous nitrate has been precipitated.
When the curve becomes steeper, the titrant addition should be slowed down. Read off the equivalence point from the graph and calculate any required data from this value. Liquid-based electrodes A mobile carrier transports the selected ion across a membrane impregnated with a liquid solution of the carrier. From Wikipedia, the free encyclopedia. Clipping is a handy way to collect important slides you want to go back to later.
Potentiometric titration is a technique similar to direct titration of a redox reaction. Wilhelm Bottger then developed the tool of potentiometric titration while working at Ostwald's Institute. Thus the potentiometric titration involve measurement of E cell with the addition of titrant. In many cases, basic dialogues in english pdf not all the endpoints detected in the titration are of interest.
The type of titration we will focus on in this session is one that uses an electrode as an indicator. This section contains some information about the basic principles of titration. Assay of cimitidine Assay. You do not have the permission to view this presentation.
Upload from Desktop Single File Upload. For example, the electrode reaction may be. The accuracy of the burette depends on the one hand on the resolution of the burette drive. It is used to measure the potential of the analyte solution comparing with that of reference electrode.
This decreased the osmotic pressure of mercury I ions on the side and creates a potential difference. In order to view it, please contact the author of the presentation.
Gases are absorbed in solutions aerosol is deposited on filters. The reference electrode is the electrode which contains of its own potential value and it is stable when dipped into sample solution. These are composed of the metal wires coated with the salt precipitates. Certain applications like the determination of sulfur dioxide in wine require a double platinum electrode.
During a titration, the burette is automatically refilled if the regent consumption is higher than the volume of the burette. The formulas needed for this calculation can be programmed and depend on type of analysis.
Arrange the calomel electrode and the paddle of the stirrer in such a way that it must be at the lower level of the glass electrode which is placed between them. The precision of the burette must thus be checked at regular intervals. To detect a loss of accuracy of the burette, regular system performance checks must be performed. It is a useful means of characterizing an acid. To add the titrant to the sample, the valve is opened towards the sample and the piston moves up.
These electrodes are also known as inert electrodes and redox electrodes. The preamplifier is located in the stirrer or the sample changer see picture on the right. In other projects Wikimedia Commons.
You just clipped your first slide! The inorganic salt is made such to have vacancies in its lattice structure.
Due to the chemical reaction taking place in the sample to be analysed, the characteristics of the sample changes. These are mainly classified into three types of electrodes used in the potentiometry. This permits charge transfer and potential measurement but not mass transfer of the acid solution in the electrode.
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